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Park Shin-Hye played the role of main character Han Jung-Seo as a child ( Choi Ji-Woo played the adult Han Jung-Seo). Park Shin-Hye was picked among 250 contestants. In the same year she also successfully auditioned for a role in the SBS drama series " Stairway to Heaven". In 2003 Park Shin-Hye debuted as the main female character in the music video "Ggot" (Flower) by singer Lee Seung-Hwan. Her family also relocated to Seoul in 2001. Through her relationship with Dream Factory, Park Shin-Hye began training as an actress, singer, and playing the guitar & keyboard. Consequently, Park Shin-Hye went to Seoul and auditioned for Dream Factory. When Park Shin-Hye was in 6th grade at Hak-Kang Elementary School in Gwangju, she was advised to audition for pop singer Lee Seung-Hwan's music company "Dream Factory" by her English teacher at a private institute. Her family consists of her parents and one older brother. Park Shin-Hye was born on Feburary 18th, 1990 in Gwangju, Jeollanam-do, South Korea.
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He is also an Officer of the Order of Canada, has been inducted into the Canadian Music Hall of Fame, received his own star on the Hollywood Walk of Fame.īryan Adams will headline London's The O2 in December 2022, which follows a run of Canadian dates and rescheduled European shows from November onwards. Bryan Adams made a last-minute exit from Saturday’s (Oct. Bryan Adams: So Happy It Hurts Tour January 25, 27-28 February 1, 3-4 8 p.m. This stellar career has earned him some of the highest honours in music and entertainment, including a Grammy, 18 Juno Awards and numerous Academy Award and Golden Globe nominations. Education He studied at the American International School of Lisbon. Though, he is 5 8 in feet and inches and 172 cm in Centimetres tall, he weighs about 158 lbs in Pound and 72kg in Kilograms. The 62-year-old singer, who is currently in Milan, revealed he had tested positive for the second time upon his arrival in Italy on Thursday (25 November). Today, his discography boasts a total of 15 studio albums including, most recently, 'So Happy It Hurts' in 2021. Well, Bryan Adams’s age is 62 years old as of today’s date 13th October 2022 having been born on 5 November 1959. Bryan Adams has tested positive for Covid-19 twice in a month. He released his self-titled debut album in 1980, and has since become a global icon in contemporary rock music. Bryan Adams is a singer-songwriter and musician from Ontario, Canada. “Don’t take this as a race,” Middleman told supporters at Savoy in the Strip District shortly after 10 p.m. (Lee herself, for one, bested a member of the noted Costa political dynasty last year.) Locally, she was bidding to be the latest in a series of progressive insurgents to challenge long-established Democrats with familiar names but little recent history of facing a challenger. She had hoped to join a group of progressives who, in recent years, have been elected district attorney in major jurisdictions, including Philadelphia. And despite Zappala’s advantage with labor, Middleman enjoyed the backing of the healthcare workers union, SEIU Healthcare Pennsylvania. She did it with over $20,000 in help from UNITE, a political committee established by state Rep. She enjoyed the support of a well-organized corps of grassroots organizers that has propelled other progressives into local office in recent years: Her campaign marshaled an aggressive ground game, and campaign finance records show that by Tuesday, it had outraised Zappala by more than $65,000.Ĭampaign finance records show Middleman brought in more than $288,000 since June, compared to about $222,000 for Zappala during the same period. Middleman, meanwhile, cast herself as the progressive alternative, advocating more sweeping proposals to eliminate monetary bail completely and to decriminalize low-level offenses. His vote totals were boosted by straight-party votes cast by voters in both parties: Such votes made up slightly more than a quarter of all ballots cast. That strategy helped clinch the victory for him. He also staged a successful write-in campaign to appear on the Republican ticket Tuesday. He prevailed in his party’s primary in May and had the backing of organized labor. The incumbent also highlighted steps he has taken to reduce the use of cash bail. The Democrat touted his 21 years of experience as district attorney while also emphasizing his openness to reforms such as “diversionary programs” meant to link low-level offenders with drug and mental health treatment and community support. He struck similar notes throughout the campaign. “We changed how we handled bail, we changed incarceration … and I’m very proud of that,” he said. “People are going to disagree.”īut after fending off a challenge from his left, Zappala touted his record as a reformer who had made progressive changes to the criminal justice sytsem. “I represent 1.25 million people … and it’s not easy,” he said. Tuesday, Zappala acknowledged the race had been contentious. Speaking to supporters gathered at Cupka’s II on Pittsburgh’s South Side around 10:30 p.m. (Pittsburgh) - Democrat Stephen Zappala will remain Allegheny County District Attorney after winning a comfortable victory against Independent Lisa Middleman in Tuesday’s election.īy 11 p.m., Zappala appeared poised to post a roughly 10-point victory in the first competitive race he has faced in years. Now, it’s time to find better ways to interact with you and ensure we meet your high standards of what a credible media organization should be.Īllegheny County District Attorney Stephen Zappala, at his victory party Tuesday night. The days of journalism’s one-way street of simply producing stories for the public have long been over. In this approximation, the electron cloud of an atom is assumed to be the superposition of charge clouds, or orbitals, arising from the individual electrons these orbitals resemble the atomic orbitals of hydrogen (for which exact solutions are known), which we described in some detail in the previous section. One of the most common and useful of these is the orbital approximation. We must therefore rely on approximations to solutions of the many- electron Schrodinger equation. The Schrodinger equation is much more complicated for atoms with more than one electron than for a one- electron species such as a hydrogen atom, and an explicit solution to this equation is not possible even for helium, let alone for more complicated atoms. The wave function for an atom simultaneously depends on (describes) all the electrons in the atom. The last formula, as is easy to prove, holds for the atomic orbitals of hydrogen atoms (see p. Earlier, people thought the orbitals decay as exp(-2c,-r), where c,- is the orbital energy expressed in atomic units. It has been proved that each of the Hartree-Fock orbitals has the same asymptotic dependence on the distance from the molecule (N.C. 23 Molecular orbital of the hydrogen molecule,, composed of the atomic orbitals of hydrogen atoms. The molecular orbitals derived for this system form the basis of the molecular orbitals for all other diatomic molecules, in much the same way that the atomic orbitals of hydrogen form the basis for all atomic orbitals. We begin our consideration of chemical bonding by looking at the simplest possible molecule, H2. Three integers are required for a complete specification. The atomic orbitals of hydrogen are labeled by quantum numbers. Positive phase for wave functions (orbitals) shown red, negative as white. įigure 7.1 Overlap of the atomic orbitals of hydrogen. However, the number of states associated with each combination of (n,, m) is twice as large because of the two values for m. The allowed quantum numbers follow the same pattern as those for the hydrogen atom. The first three quantum numbers describe its spatial distribution and the fourth specifies its spin state. Each electron in an atom has associated with it a set of four quantum numbers (n,, m, mfj. The lowest energy orbital is a Is orbital and has no radial nodes, the next lowest s orbital is a 2s orbital and has one radial node, and so forth. The radial dependence of the orbitals in many-electron atoms differs from that of one- electron orbitals because the effective field differs from the Coulomb potential, but a principal quantum number n can still be defined. Their angular dependence is identical to that of the hydrogen orbitals, so quantum numbers and m are associated with each atomic orbital. These Hartree orbitals resemble the atomic orbitals of hydrogen in many ways. At first sight, the bond is a simple one, compounded of the Is and the atomic orbitals of hydrogen and halogen respectively. The decrease in ionic character from hydrogen fluoride to hydrogen iodide is marked and due to increasing symmetry in the distribution of the bonding electrons. These units are actually derived from the solution of the H these quantities are used to define the units of angular momentum, mass and charge respectively. In au ft = 1, tWe = 1 and the electron charge e = I, i.e. If we switch to atomic units (au) then the manipulation and solution of this formula becomes clearer because we remove the clutter of the physical constants. To calculate wavefunctions for any stationary state of an H-like atom we would like solutions to the Schrbdinger equation Įquation (A9.1) assumes nothing about the units of the quantities used. For a qualitative insight into chemical bonding, these can be reintroduced later. This avoids the complication of considering electron-electron interactions. īy H-like we mean that a solitary electron moves in the field of a positively charged nucleus. We will also take the opportunity to cover some basic ideas in quantum mechanics. In this appendix we show how solutions of the Schrodinger equation for H-like atoms give us the atomic orbitals that are used as the building blocks in this approach. The discussion of chemical bonding in the main text depends on the description of molecular orbitals as linear combinations of atomic orbitals. Tertuliano MáximoĚfonso is greatly in need of stimuli to distract him, he lives alone and gets bored, or, to speak with the clinical exactitude that the present day requires, he has succumbed to the temporary weakness of spirit ordinarily known as depression. He is a history teacher at a secondary school, and a colleague had suggested the video to him with the warning, It's not exactly a masterpiece of cinema, but it might keep you amused for an hour and a half. The Máximo and theĚfonso, which are in more common usage, he can just about tolerate, depending, of course, on the mood he's in, but the Tertuliano weighs on him like a gravestone and has done ever since he first realized that the wretched name lent itself to being spoken in an ironic, potentially offensive tone. THE MAN WHO HAS JUSTĜOME INTO THE SHOP TO RENTĚ video bears on his identity card a most unusual name, a name with a classical flavor that time has staled, neither more nor less than Tertuliano MáximoĚfonso. I believe in my conscience I intercept many a thought The double/José Saramago translated from the Portuguese The Library ofĜongress has cataloged the print edition as follows: Saramago, José. This is a translation of O Homemĝuplicado. ParkĚvenue South, New York, New Yorkđ0003. No part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher.įor information about permission to reproduce selections from this book, write to Permissions, Houghton Mifflin Harcourt PublishingĜompany,Ē15 © José Saramago eĞditorialĜaminho, SAĒ002Įnglish translation copyright © Margaret JullĜosta,Ē004Īll rights reserved. Use MAP Themes to create thematic maps, designate point symbols, and apply graphic styles based on rules that you create.Ĭreate labels using the Label Features tool to automatically place labels to map features and fine-tune the labeling with Map Tagger. Save time by styling map data based on its attributes. Create new features on-the-fly, maintain georeferencing when joining, cropping, trimming, buffering, and simplifying data. 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It is found on the skin to keep it hydrated.Magnesium It contributes to the maintenance of bones under normal conditions, the normal functioning of muscles and the synthesis of proteins, including collagen, under normal conditions. It is found naturally in the body, where it acts as a lubricant in the joints. It helps the flexibility and mobility of the joints.Hyaluronic acid It is a very abundant polysaccharide in the synovial fluid of the joints and skin. Proteins, like collagen, contribute to maintaining and increasing muscle mass, as well as maintaining bones in normal conditions.Silicon Silicon is an essential trace element for the organism that is found in tendons, hair, nails, skin and joints. Another component of data worthy of exploration is whether the antioxidants found in wine, such as revesterol or polyphenols, have a protective effect on bone in addition to other health benefits.Bioassimilable hydrolyzed collagen It is the essential protein for joints, cartilage, tendons, ligaments, bones and skin. “Future studies might dig deeper into patterns of alcohol consumption, as we relied on a self-reported dietary questionnaire. “We cannot say definitively what component of these alcoholic drinks might be beneficial to bone health, because our findings are from an observational study as opposed to a clinical trial,” Tucker says. It is less clear why liquor and wine might protect bone mineral density. Previous studies have found that silicon has greater bioavailability as a liquid. The authors hypothesize that the silicon in beer contributed to the higher bone mineral density scores in the men who reported consuming one or two servings of total alcohol or beer per day. No one should depend solely on alcohol to maintain bone health.” “It’s a major risk factor for osteoporosis. “There is a body of research showing alcoholism is devastating to bones,” Tucker says. In contrast, the authors observed significantly lower bone mineral density at the hip and spine in men who consumed more than two servings of liquor per day compared to men who consumed one or two servings of liquor per day. Hip bone mineral density in this group was significantly greater compared to non-drinkers. One of the strongest associations was seen in men who reported consuming one or two servings of total alcohol (a combination of beer, wine and liquor) or one or two servings of beer per day. One serving of wine equaled a 4-ounce glass, and one serving of liquor equaled one mixed drink or shot.Īfter adjusting for other factors that may have accounted for the higher bone mineral density, such as silicon intake, calcium intake and smoking history, the authors saw an association between higher bone mineral density and moderate alcohol consumption. One serving of beer equaled a glass, bottle or can. Participants self-reported their alcohol intake on dietary questionnaires. There was not enough data to determine the effects of more than two servings of alcohol per day in post-menopausal women or the effects of daily alcohol consumption on bone mineral density in pre-menopausal women. Tucker, who is also an adjunct associate professor of family medicine and community health at Tufts Medical School, and her colleagues analyzed bone mineral density measurements taken at three hip sites and the lumbar spine in 1,182 men, 1,289 post-menopausal women and 248 pre-menopausal women whose parents or in-laws participated in the original Framingham Heart Study. “We saw stronger associations between higher bone mineral density and beer drinkers, who were mostly men, and wine drinkers, who were mostly women, compared to liquor drinkers.” The results were published in late February in the American Journal of Clinical Nutrition. “Our study also looks at the possible effects of the three alcohol classes, beer, wine and liquor, on bone mineral density,” says Tucker, who is also a professor at the Friedman School of Nutrition Science and Policy. The 2005 dietary guidelines issued by the federal government define moderate alcohol consumption as one drink a day for women and two drinks daily for men. “Previous research suggests that moderate alcohol consumption in older men and post-menopausal women may protect against bone mineral density loss, a major risk factor for osteoporosis,” says Katherine Tucker, director of the Dietary Assessment and Epidemiology Research Program at the HNRCA. Research suggests that regular moderate consumption of beer or wine may have protective effects on bone, but that heavy drinking may contribute to bone loss. |
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